The Amazing Spider-Man #338 (1990)
“Return of the Sinister Six, Part Five: Death From Above”
Writer: David Michelinie
Artist: Erik Larsen
Somebody tries to kill Peter as he walks down the sidewalk. MJ suspects Jonathan Caesar. She looks at guns on the way to work. Jonathan Caesar makes her director write a note to meet him and then kills him. At the satellite launch, the Sinister Six attacks and Peter changes into Spider-Man and goes into action. He gets some good punches in, but Ock’s plan eventually goes into motion and the poison is placed and the rocket is launched. Sandman turns on Ock and the rest, threats be damned, and then Ock turns him into glass. Hobgoblin sprays Spidey with poison and says he has 15 seconds to live.