The Amazing Spider-Man #001 (1963)
Writer: Stan Lee
Artist: Steve Ditko
J. Jonah Jameson’s son is an astronaut and is setting off into space when the capsule goes out of control and it’s up to Spider-Man to save him.
“Spider-Man vs. The Chameleon!”
Spider-Man is short on cash so he tries to join the Fantastic Four, but leaves when he finds out it’s a non-profit business with no salaries. Meanwile The Chameleon hears of Spider-Man and frames him for a robbery. Spider-Man finds The Chameleon and brings him to the police but he escapes. They eventually see him because of the Spider-Man suit beneath his jacket.